Janna Jeschke et al. “Multicomponent molecular editing of polybutadiene: from design space to battery function.” ChemRxiv (). https://doi.org/10.26434/chemrxiv.15007590/v1

Functionalized polybutadiene
Identifier P1
SEC (THF, linear polystyrene standards) Apparent Mₙ = 17100 g mol⁻¹; Đ = 1.08
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 20329 g mol⁻¹; Đ = 1.19
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 21 °C
TGA temperature at 10 % mass loss 159 °C
Main, pp. 9–10; SI, pp. S56, S77
Functionalized polybutadiene
Identifier P2
SEC (THF, linear polystyrene standards) Apparent Mₙ = 18200 g mol⁻¹; Đ = 1.08
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 56 °C
TGA temperature at 10 % mass loss 173 °C
TEM (SI report) No pronounced nanoscale contrast under the applied imaging conditions
Main, pp. 9–10; SI, pp. S12, S72, S77
Functionalized polybutadiene
Identifier P3
SEC (THF, linear polystyrene standards) Apparent Mₙ = 20200 g mol⁻¹; Đ = 1.18
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 24968 g mol⁻¹; Đ = 1.14
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 58 °C
TGA temperature at 10 % mass loss 179 °C
SEC apparent dispersity (THF; main-text report) Đ = 1.53
TEM (SI report) Weak nanoscale contrast
Main, pp. 8–10; SI, pp. S12, S56, S72, S77
Functionalized polybutadiene
Identifier P4
SEC (THF, linear polystyrene standards) Apparent Mₙ = 21300 g mol⁻¹; Đ = 1.26
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 51 °C
TGA temperature at 10 % mass loss 171 °C
Main, pp. 9–10; SI, p. S77
Functionalized polybutadiene
Identifier P5
SEC (THF, linear polystyrene standards) Apparent Mₙ = 21400 g mol⁻¹; Đ = 1.93
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 25463 g mol⁻¹; Đ = 1.69
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 32 °C
TGA temperature at 10 % mass loss 163 °C
Main, pp. 8–11; SI, pp. S56, S77
Functionalized polybutadiene
Identifier P6
SEC (THF, linear polystyrene standards) Apparent Mₙ = 19000 g mol⁻¹; Đ = 1.25
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 43 °C
TGA temperature at 10 % mass loss 170 °C
Main, pp. 8–11; SI, p. S77
Functionalized polybutadiene
Identifier P7
SEC (THF, linear polystyrene standards) Apparent Mₙ = 15000 g mol⁻¹; Đ = 1.18
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 17672 g mol⁻¹; Đ = 1.21
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 50 °C
TGA temperature at 10 % mass loss 167 °C
¹H–¹³C HSQC NMR (CDCl₃) Correlation between the characteristic carbon resonance at ~80 ppm and adjacent proton resonances of the incorporated ether unit at 4.1 and 3.3 ppm
Main, pp. 8–10; SI, pp. S22, S57, S77
Functionalized polybutadiene
Identifier P8
SEC (THF, linear polystyrene standards) Apparent Mₙ = 15100 g mol⁻¹; Đ = 1.19
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 18860 g mol⁻¹; Đ = 1.15
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 64 °C
TGA temperature at 10 % mass loss 178 °C
Main, pp. 9–10; SI, pp. S57, S77
Functionalized polybutadiene
Identifier P9
SEC (THF, linear polystyrene standards) Apparent Mₙ = 18600 g mol⁻¹; Đ = 1.48
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 58 °C
TGA temperature at 10 % mass loss 178 °C
TEM (SI report) Lamellar nanoscale contrast with characteristic spacings of approximately 20–30 nm
AFM Heterogeneous surface morphology; mean Feret diameter 207 ± 66 nm
Main, pp. 9–10, 12; SI, pp. S12–S13, S71, S73, S77
Functionalized polybutadiene
Identifier P10
SEC (THF, linear polystyrene standards) Apparent Mₙ = 19400 g mol⁻¹; Đ = 1.22
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 22260 g mol⁻¹; Đ = 1.15
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 53 °C
TGA temperature at 10 % mass loss 181 °C
Main, pp. 9–11; SI, pp. S58, S77
Functionalized polybutadiene
Identifier P11
SEC (THF, linear polystyrene standards) Apparent Mₙ = 14600 g mol⁻¹; Đ = 1.17
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 22801 g mol⁻¹; Đ = 1.20
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 45 °C
TGA temperature at 10 % mass loss 155 °C
Main, pp. 9–11; SI, pp. S58, S77
Functionalized polybutadiene
Identifier P12
SEC (THF, linear polystyrene standards) Apparent Mₙ = 16000 g mol⁻¹; Đ = 1.12
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 19160 g mol⁻¹; Đ = 1.17
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 67 °C
TGA temperature at 10 % mass loss 162 °C
Main, pp. 9–11; SI, pp. S59, S77
Functionalized polybutadiene
Identifier P13
SEC (THF, linear polystyrene standards) Apparent Mₙ = 15100 g mol⁻¹; Đ = 1.65
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 23166 g mol⁻¹; Đ = 1.50
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 53 °C
TGA temperature at 10 % mass loss 158 °C
Main, pp. 9–10; SI, pp. S59, S77
Functionalized polybutadiene
Identifier P14
SEC (THF, linear polystyrene standards) Apparent Mₙ = 14300 g mol⁻¹; Đ = 1.36
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 18218 g mol⁻¹; Đ = 1.34
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 59 °C
TGA temperature at 10 % mass loss 174 °C
Main, pp. 9–10; SI, pp. S60, S77
Functionalized polybutadiene
Identifier P15
SEC (THF, linear polystyrene standards) Apparent Mₙ = 12500 g mol⁻¹; Đ = 1.53
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 23807 g mol⁻¹; Đ = 1.20
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 50 °C
TGA temperature at 10 % mass loss 175 °C
Main, pp. 9–10; SI, pp. S60, S77
Functionalized polybutadiene
Identifier P16
SEC (THF, linear polystyrene standards) Apparent Mₙ = 18600 g mol⁻¹; Đ = 1.30
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 23858 g mol⁻¹; Đ = 1.21
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 40 °C
TGA temperature at 10 % mass loss 185 °C
Main, pp. 9–11; SI, pp. S61, S77
Functionalized polybutadiene
Identifier P17
SEC (THF, linear polystyrene standards) Apparent Mₙ = 13325 g mol⁻¹; Đ = 1.23
SEC (DMAc with LiBr, polystyrene standards, 50 °C, 1.0 mL min⁻¹) Apparent Mₙ = 23622 g mol⁻¹; Đ = 1.21
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 67 °C
TGA temperature at 10 % mass loss 157 °C
Main, pp. 8–11; SI, pp. S61, S77
Functionalized polybutadiene
Identifier P18
SEC (THF, linear polystyrene standards) Apparent Mₙ = 15900 g mol⁻¹; Đ = 1.14
DSC glass transition temperature (second heating cycle; inflection point of heat-capacity transition) 60 °C
TGA temperature at 10 % mass loss 163 °C
Main, pp. 8–11; SI, p. S77
Functionalized polybutadienes
Identifiers P8 and P9
TEM Whereas P8 displayed comparatively weak contrast, P9 exhibited pronounced, regularly spaced contrast features with a characteristic separation of approximately 30 nm
Main, p. 12
Functionalized polybutadienes
Identifiers P2, P3, and P9
TEM The p-nitrobenzenesulfonamide-containing polymer P3 exhibited more pronounced nanoscale contrast than its p-toluenesulfonamide counterpart P2, although the contrast in P3 was somewhat weaker than that observed for the corresponding 2-MeTHF-derived polymer P9
Main, p. 12
Pristine polybutadiene and functionalized polybutadienes
Identifiers PBD, P8, and P9
Low-field ¹H NMR conditions Bruker Minispec MQ-20; 10 mm NMR tube; 20 MHz; static conditions; 45 °C; inversion–recovery sequence 180°–τ–90°–acquisition
Inversion–recovery fit Monoexponential ExpDec1; t₁ = T₁,eff; uncertainties are standard errors of the fitted t₁ parameter
Effective longitudinal relaxation time PBD 149 ± 1 ms; P8 172 ± 1 ms; P9 262 ± 2 ms
Effective relaxation-time reporting qualifier Because the measurements represent the collective response of the detected proton environments within the polymers, the fitted values are treated as comparative effective relaxation times rather than relaxation times assigned to individual structural domains
FID/echo amplitude normalization Each amplitude divided by the maximum amplitude of the corresponding FID; normalized FID maximum assigned 1
Normalized SE/FID amplitude ratio P8 1.12; P9 1.22
Normalized MSE/FID amplitude ratio P8 1.12; P9 1.30
Apparent FID signal-loss calculation Lₖ (%) = 100 (1 − 1/Rₖ), k = SE or MSE
Apparent FID signal loss PBD no positive apparent FID signal loss was assigned; P8 11 % relative to both SE and MSE; P9 18 % relative to SE and 23 % relative to MSE
Amplitude-ratio and apparent-signal-loss reporting qualifier These amplitude ratios and apparent signal-loss values are used as comparative, pulse-sequence-dependent mobility descriptors. They are not interpreted as absolute rigid- or mobile-proton fractions, because the measured amplitudes may additionally depend on experimental factors such as receiver dead time, echo timing, pulse calibration, and the refocusing efficiency of the respective pulse sequences
Main, pp. 12–13; SI, pp. S12–S13, S74–S76
Functionalized polybutadienes
Identifiers P11 and P12
FTIR N–H stretching vibrations characteristic of the sulfonamide derivatives were absent, while characteristic S=O absorption bands were retained
Main, p. 8
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P1
FTIR (transmission mode, thin films on KBr plates) 3291 cm⁻¹ (ν-NH); 3076 cm⁻¹ (ν-C=CH); 1315 cm⁻¹ (ν-S=O); 1155 cm⁻¹ (ν-S=O); 1079 cm⁻¹ (ν-C-O); 962 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 914 cm⁻¹ (γ-C=CH)₁,₂-PBD; 727 cm⁻¹ (γ-C=CH)cis
SI, p. S42
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P2
FTIR (transmission mode, thin films on KBr plates) 3282 cm⁻¹ (ν-NH); 3076 cm⁻¹ (ν-C=CH); 1332 cm⁻¹ (ν-S=O); 1160 cm⁻¹ (ν-S=O); 1090 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S42
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P3
FTIR (transmission mode, thin films on KBr plates) 3216 cm⁻¹ (ν-NH); 3076 cm⁻¹ (ν-C=CH); 1540 cm⁻¹ (ν-NO₂); 1170 cm⁻¹ (ν-S=O); 1090 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S43
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P4
FTIR (transmission mode, thin films on KBr plates) 3296 cm⁻¹ (ν-NH); 3076 cm⁻¹ (ν-C=CH); 1332 cm⁻¹ (ν-S=O); 1169 cm⁻¹ (ν-CF₃); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S43
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P5
FTIR (transmission mode, thin films on KBr plates) 3076 cm⁻¹ (ν-C=CH); 1357 cm⁻¹ (ν-S=O); 1176 cm⁻¹ (ν-S=O); 1090 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S44
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P6
FTIR (transmission mode, thin films on KBr plates) 3076 cm⁻¹ (ν-C=CH); 1363 cm⁻¹ (ν-S=O); 1178 cm⁻¹ (ν-S=O); 1091 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S44
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P7
FTIR (transmission mode, thin films on KBr plates) 3298 cm⁻¹ (ν-NH); 3076 cm⁻¹ (ν-C=CH); 1321 cm⁻¹ (ν-S=O); 1153 cm⁻¹ (ν-S=O); 1082 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S45
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P8
FTIR (transmission mode, thin films on KBr plates) 3290 cm⁻¹ (ν-NH); 3076 cm⁻¹ (ν-C=CH); 1332 cm⁻¹ (ν-S=O); 1162 cm⁻¹ (ν-S=O); 1093 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S45
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P9
FTIR (transmission mode, thin films on KBr plates) 3300 cm⁻¹ (ν-NH); 3076 cm⁻¹ (ν-C=CH); 1533 cm⁻¹ (ν-NO)NO₂; 1315 cm⁻¹ (ν-S=O); 1168 cm⁻¹ (ν-S=O); 1093 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S46
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P10
FTIR (transmission mode, thin films on KBr plates) 3300 cm⁻¹ (ν-NH); 3076 cm⁻¹ (ν-C=CH); 1166 cm⁻¹ (ν-C-F)CF₃; 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S46
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P11
FTIR (transmission mode, thin films on KBr plates) 3076 cm⁻¹ (ν-C=CH); 1361 cm⁻¹ (ν-S=O); 1176 cm⁻¹ (ν-S=O); 1090 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S47
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P12
FTIR (transmission mode, thin films on KBr plates) 3076 cm⁻¹ (ν-C=CH); 1367 cm⁻¹ (ν-S=O); 1180 cm⁻¹ (ν-S=O); 1095 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S47
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P13
FTIR (transmission mode, thin films on KBr plates) 3300 cm⁻¹ (ν-NH); 3076 cm⁻¹ (ν-C=CH); 1321 cm⁻¹ (ν-S=O); 1153 cm⁻¹ (ν-S=O); 1093 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S48
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P14
FTIR (transmission mode, thin films on KBr plates) 3292 cm⁻¹ (ν-NH); 3076 cm⁻¹ (ν-C=CH); 1332 cm⁻¹ (ν-S=O); 1162 cm⁻¹ (ν-S=O); 1093 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S48
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P15
FTIR (transmission mode, thin films on KBr plates) 3290 cm⁻¹ (ν-NH); 3076 cm⁻¹ (ν-C=CH); 1533 cm⁻¹ (ν-NO)NO₂; 1315 cm⁻¹ (ν-S=O); 1162 cm⁻¹ (ν-S=O); 1095 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S49
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P16
FTIR (transmission mode, thin films on KBr plates) 3300 cm⁻¹ (ν-NH); 3076 cm⁻¹ (ν-C=CH); 1320 cm⁻¹ (ν-S=O); 1166 cm⁻¹ (ν-C-F)CF₃; 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S49
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P17
FTIR (transmission mode, thin films on KBr plates) 3076 cm⁻¹ (ν-C=CH); 1361 cm⁻¹ (ν-S=O); 1176 cm⁻¹ (ν-S=O); 1090 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S50
Pristine PBD and functionalized polybutadiene
Identifiers PBD and P18
FTIR (transmission mode, thin films on KBr plates) 3076 cm⁻¹ (ν-C=CH); 1367 cm⁻¹ (ν-S=O); 1180 cm⁻¹ (ν-S=O); 1095 cm⁻¹ (ν-C-O); 968 cm⁻¹ (γ-C=CH)ₜᵣₐₙₛ; 912 cm⁻¹ (γ-C=CH)₁,₂-PBD; 728 cm⁻¹ (γ-C=CH)cis
SI, p. S50
Pristine polybutadiene
SEC (THF, linear polystyrene standards) Apparent Mₙ = 8900 g mol⁻¹; Đ = 1.06
Main, p. 8; SI, p. S77
Functionalized polybutadiene library
Identifiers P1–P18
NMR observation Quantitative consumption of the PBD double bonds observed by NMR spectroscopy
qNMR functionalization-degree basis 1,4-dimethoxybenzene internal standard; remaining repeating units were assumed to be monobrominate
Quantitative ¹H NMR functionalized repeating units P1 20 mol%; P2 30 mol%; P3 34 mol%; P4 32 mol%; P5 25 mol%; P6 38 mol%; P7 11 mol%; P8 17 mol%; P9 34 mol%; P10 22 mol%; P11 40 mol%; P12 59 mol%; P13 17 mol%; P14 30 mol%; P15 39 mol%; P16 36 mol%; P17 58 mol%; P18 68 mol%
Linear-fit variables Glass transition temperature versus functionalization degree
Linear-fit equation y = a + b*x
Linear-fit weighting No Weighting
Intercept 40,669 ± 6,589
Slope 0,32 ± 0,178
Residual sum of squares 2027.72143
Pearson's r 0.4096
R-Square (COD) 0.16777
Adjusted R-Square 0.11576
Sensitivity-analysis basis Descriptive sums-of-squares decomposition of the 18-member, 3 × 6 molecular design space; one polymer per cyclic ether–nucleophile combination; remaining variation cannot be partitioned into interaction and experimental residual sums of squares; descriptive rather than inferential ANOVA
Functionalization degree grand mean 33.89 mol%
Functionalization degree cyclic-ether means THF 29.83 mol%; 2-MeTHF 30.50 mol%; THP 41.33 mol%
Functionalization degree nucleophile-specific mean range 16.00–55.00 mol%
Functionalization degree variation contributions Cyclic ether 12.50 %; nucleophile 67.63 %; remaining/non-additive 19.87 %
Glass transition temperature grand mean 51.50 °C
Glass transition temperature cyclic-ether means THF 43.50 °C; 2-MeTHF 56.17 °C; THP 54.83 °C
Glass transition temperature nucleophile-specific mean range 41.33–59.67 °C
Glass transition temperature variation contributions Cyclic ether 23.86 %; nucleophile 29.05 %; remaining/non-additive 47.09 %
Temperature at 10 % mass loss grand mean 169.33 °C
Temperature at 10 % mass loss cyclic-ether means THF 169.17 °C; 2-MeTHF 170.17 °C; THP 168.67 °C
Temperature at 10 % mass loss nucleophile-specific mean range 158.33–179.00 °C
Temperature at 10 % mass loss variation contributions Cyclic ether 0.49 %; nucleophile 82.63 %; remaining/non-additive 16.88 %