Christopher Adamson, Lanxin Li, Evan Ng Wei Long, Han-Yi Huang, Alexandre Persat, Yuan Qiao. “Total synthesis and preliminary biological evaluation of the natural glycolipids cupacinoside and dalberoside.” ChemRxiv (). https://doi.org/10.26434/chemrxiv.15007733/v1

The main paper refers to supporting information, but no separate supporting information file was found among the files available from the ChemRxiv record

Synthetic and natural cupacinoside
¹³C NMR chemical-shift comparison Chemical shifts differ by at most 0.24 ppm
Main, p. 4
Disaccharide 14
¹H NMR Nascent anomeric position: δ 5.32 ppm, d, J = 1.6 Hz
¹³C NMR Nascent anomeric position: δ 99.2 ppm
Main, p. 7
Intermediate 17 and subsequent intermediates containing a tris-TBS-protected rhamnose
¹H and ¹³C NMR Broadened peaks
Main, p. 7
Diol 21
HMBC The presence of the propargyl group at C-4 was apparent from HMBC correlations
Main, p. 7
Trisaccharide 28b
¹H NMR Nascent anomeric position: δ 4.57 ppm, d, J = 2.0 Hz
¹³C NMR Nascent anomeric position: δ 101.0 ppm