Sana Farhoudian, Shawon Barua, Avinash Kumar, Dominika Pasik, Sakshi Jha, Rabbia Asgher, Nanna Myllys, Matti Rissanen. “NO-driven radical propagation enables accretion-product formation in cis-decalin oxidation.” ChemRxiv (). https://doi.org/10.26434/chemrxiv.15007876/v1

Values presented only in CIMS spectra or time-series plots or images were not transcribed. The main paper refers to supporting information, but no separate supporting information file was available on the ChemRxiv article page

Cis-decalin •OH-oxidation products
Br⁻ CIMS, 0.9 s, no NO Weak C₁₀H₁₆O₃ signal
NO₃⁻ CIMS, 2.9 s, no NO Trace C₁₀H₁₇O₆,₇• signals
Br⁻ CIMS, 0.9 s, 40 ppb NO C₁₀H₁₆O₃ signal increased; C₁₀H₁₆O₄,₅ monomers, C₁₀H₁₇O₄–₆NO organo-nitrates, C₁₀H₁₇O₄,₅• radicals, and C₉H₁₆O₃ fragmentation product were detected
Br⁻ CIMS, 0.9 s, 300 ppb NO Organo-nitrate signals became dominant; C₉H₁₆O₄,₅ fragmentation products were detected
NO₃⁻ CIMS, 2.9 s, 40 ppb NO C₁₀H₁₆O₇ had the highest monomer signal intensity and C₂₀H₃₄O₈ was the most abundant accretion product
NO₃⁻ CIMS, 2.9 s, 300 ppb NO Accretion products were not detected and organo-nitrate signals were strongly enhanced
NO₃⁻ CIMS, 2.9 s, early-stage oxygenated products C₁₀H₁₆,₁₇,₁₈O₄; C₁₀H₁₆,₁₇,₁₈O₅; C₁₀H₁₆,₁₇,₁₈O₆
NO₃⁻ CIMS, 2.9 s, highly oxygenated products C₁₀H₁₆,₁₇,₁₈O₇; C₁₀H₁₆,₁₇,₁₈O₈; C₁₀H₁₆,₁₇O₉; C₁₀H₁₆O₁₀
NO₃⁻ CIMS, 2.9 s, organo-nitrates C₁₀H₁₇O₄NO; C₁₀H₁₇O₅NO; C₁₀H₁₇O₆NO; C₁₀H₁₇O₇NO; C₁₀H₁₇O₈NO; C₁₀H₁₇O₉NO; C₁₀H₁₇O₁₀NO
NO₃⁻ CIMS, 2.9 s, accretion products C₂₀H₃₄O₆; C₂₀H₃₄O₇; C₂₀H₃₄O₈; C₂₀H₃₄O₉; C₂₀H₃₄O₁₀
NO₃⁻ CIMS, 2.9 s, fragmentation products C₈H₁₂O₅; C₈H₁₄O₆; C₉H₁₆O₄; C₉H₁₄,₁₆O₅; C₉H₁₄,₁₆O₆; C₉H₁₄,₁₆O₇; C₉H₁₄O₈
NO₃⁻ CIMS, 2.9 s, fragmentation organo-nitrates C₉H₁₅O₅NO; C₉H₁₅O₆NO; C₉H₁₅O₇NO; C₉H₁₅O₈NO
Br⁻ CIMS, 0.9 s, early-stage oxygenated products C₁₀H₁₆O₃; C₁₀H₁₆,₁₇O₄; C₁₀H₁₆,₁₇O₅
Br⁻ CIMS, 0.9 s, fragmentation products C₉H₁₆O₃; C₉H₁₆O₄; C₉H₁₆O₅
Br⁻ CIMS, 0.9 s, organo-nitrates C₁₀H₁₇O₃NO; C₁₀H₁₇O₄NO; C₁₀H₁₇O₅NO; C₁₀H₁₇O₆NO