| Fluorescence quenching of Ir[dF(CF₃)ppy]₂(dtbbpy)PF₆, photocatalyst 1 × 10⁻⁵ M, quencher 1 × 10⁻² M | Efficient quenching was observed; 1a had a greater Stern–Volmer slope than 2a |
|---|---|
| Cyclic voltammetry, degassed 1,2-dichloroethane, Ag/AgNO₃ reference electrode | Oxidation potential: +1.87 V vs. SCE; reduction potential: −1.17 V vs. SCE |
Subarna Roy, Gungun Das, Mahendra Dinkar Jadhav, Majid Ahmad Ganie, Debayan Sarkar. “Overcoming homodimerization: visible-light induced energy-transfer catalyzed crossed [2+2] cycloaddition of aryl terminal olefins.” ChemRxiv (). https://doi.org/10.26434/chemrxiv.15007959/v1
Values presented only in fluorescence spectra, Stern–Volmer plots, voltammograms, or other plots or images were not transcribed. The main paper refers to supporting information, but no separate supporting information file was available on the ChemRxiv article page
| Fluorescence quenching of Ir[dF(CF₃)ppy]₂(dtbbpy)PF₆, photocatalyst 1 × 10⁻⁵ M, quencher 1 × 10⁻² M | Efficient quenching was observed; 2a had a smaller Stern–Volmer slope than 1a |
|---|---|
| Cyclic voltammetry, degassed 1,2-dichloroethane, Ag/AgNO₃ reference electrode | Oxidation potential: +3.43 V vs. SCE; reduction potential: −2.23 V vs. SCE |